Beilstein J. Org. Chem.2019,15, 1394–1406, doi:10.3762/bjoc.15.139
luminescentdyes. Fluorescein, eosin Y, rose bengal, tetraphenylporphine sulfonate and sulfonated aluminum phthalocyanine were employed as classical aggregation-induced quenching dyes. 2-(p-Toluidinyl)naphthalene-6-sulfonic acid and 1-anilinonaphthalene-8-sulfonic acid were selected as representatives of
and potential applications according to the diverse photophysical responses are provided.
Keywords: calixarene; host–guest complexation; luminescentdyes; macrocycles; photophysical properties; Introduction
Fluorescence sensing represents a powerful detection methodology due to its low cost, ease of
fluorophores through supramolecular encapsulation using artificial macrocyclic hosts has always been an active research area [10][11][12]. The complexes of macrocycles with luminescentdyes not only act as reporter pairs for sensing [13][14][15], but also offer various applications in bioimaging [16][17
PDF
Graphical Abstract
Scheme 1:
(a) Schematic illustration of IDA. The addition of an analyte competitor leads to switch-on or swit...
Beilstein J. Org. Chem.2017,13, 768–778, doi:10.3762/bjoc.13.76
molecules with inorganic silica hosts [11][20]. Therefore, a terminal triethoxysilyl group has to be coupled to luminescentdyes with blue, green, and red emission characteristics for generating hybrid materials with white light emission based upon additive color mixing. A rapid and versatile
PDF
Graphical Abstract
Scheme 1:
Synthesis of the triethoxysilyl-functionalized dye precursors 8, 9, and 10.